Synthesis and characterization of porphyrin electrochromic and photovoltaic electropolymers
Identifieur interne : 001444 ( Main/Repository ); précédent : 001443; suivant : 001445Synthesis and characterization of porphyrin electrochromic and photovoltaic electropolymers
Auteurs : RBID : Pascal:12-0179196Descripteurs français
- Pascal (Inist)
- Porphyrine, Dispositif électrochromique, Electrochromisme, Propriété électrochimique, Addition étain, Couche ITO, Oxydation, Effet photoinduit, Séparation charge, Etat charge, Dispositif optoélectronique, Tension photoélectrique surface, Zinc, Composé conjugué, Matériau semitransparent, Oxyde d'indium, Carbazole, Amine aromatique polycyclique, Matériau dopé, ITO.
- Wicri :
- concept : Zinc.
English descriptors
- KwdEn :
- Carbazole, Charge separation, Conjugated compound, Doped materials, Electrochemical properties, Electrochromic device, Electrochromism, ITO layers, Indium oxide, Optoelectronic device, Oxidation, Photoinduced effect, Polycyclic aromatic amines, Porphyrin, Semitransparent material, State of charge, Surface photovoltage, Tin addition, Zinc.
Abstract
New asymmetric porphyrins, with electroactive functionalities were synthesized. 5,15-Bis[4(-N,N-diphenylamino)phenyl]-10,20-bis[3-(N-ethylcarbazoyl)]porphyrin and its Zn(II) derivative allow the electrochemical formation of conjugated, conducting and stable polymeric films over semitransparent indium-tin oxide surface. The spectral changes observed upon oxidation of the films produced different colorations. The polymeric materials showed the generation of photoinduced charge separation states and charge migration upon porphyrin excitation, making them promising candidates for application in optoelectronics devices.
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Morales</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Química, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Río Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Argentine</country><wicri:noRegion>Córdoba</wicri:noRegion></affiliation></author><author><name sortKey="Santo, Marisa" uniqKey="Santo M">Marisa Santo</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Departamento de Física, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Rio Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>3 aut.</sZ></inist:fA14><country>Argentine</country><wicri:noRegion>Córdoba</wicri:noRegion></affiliation></author><author><name sortKey="Funes, Matias" uniqKey="Funes M">Matias Funes</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Química, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Río Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Argentine</country><wicri:noRegion>Córdoba</wicri:noRegion></affiliation></author><author><name sortKey="Durantini, Edgardo N" uniqKey="Durantini E">Edgardo N. Durantini</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Química, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Río Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Argentine</country><wicri:noRegion>Córdoba</wicri:noRegion></affiliation></author><author><name sortKey="Fungo, Fernando" uniqKey="Fungo F">Fernando Fungo</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Química, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Río Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Argentine</country><wicri:noRegion>Córdoba</wicri:noRegion></affiliation></author><author><name sortKey="Dittrich, Thomas" uniqKey="Dittrich T">Thomas Dittrich</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Helmholtz Center Berlin for Materials and Energy, Institute of Heterogeneous Materials, Hahn-Meitner-Platz 1</s1><s2>14109 Berlin</s2><s3>DEU</s3><sZ>7 aut.</sZ></inist:fA14><country>Allemagne</country><placeName><region type="land" nuts="3">Berlin</region><settlement type="city">Berlin</settlement></placeName></affiliation></author><author><name sortKey="Otero, Luis" uniqKey="Otero L">Luis Otero</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Química, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Río Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Argentine</country><wicri:noRegion>Córdoba</wicri:noRegion></affiliation></author><author><name sortKey="Gervaldo, Miguel" uniqKey="Gervaldo M">Miguel Gervaldo</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Química, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Río Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Argentine</country><wicri:noRegion>Córdoba</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">12-0179196</idno><date when="2012">2012</date><idno type="stanalyst">PASCAL 12-0179196 INIST</idno><idno type="RBID">Pascal:12-0179196</idno><idno type="wicri:Area/Main/Corpus">001F23</idno><idno type="wicri:Area/Main/Repository">001444</idno></publicationStmt><seriesStmt><idno type="ISSN">1566-1199</idno><title level="j" type="abbreviated">Org. electron. : (Print)</title><title level="j" type="main">Organic electronics : (Print)</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Carbazole</term><term>Charge separation</term><term>Conjugated compound</term><term>Doped materials</term><term>Electrochemical properties</term><term>Electrochromic device</term><term>Electrochromism</term><term>ITO layers</term><term>Indium oxide</term><term>Optoelectronic device</term><term>Oxidation</term><term>Photoinduced effect</term><term>Polycyclic aromatic amines</term><term>Porphyrin</term><term>Semitransparent material</term><term>State of charge</term><term>Surface photovoltage</term><term>Tin addition</term><term>Zinc</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Porphyrine</term><term>Dispositif électrochromique</term><term>Electrochromisme</term><term>Propriété électrochimique</term><term>Addition étain</term><term>Couche ITO</term><term>Oxydation</term><term>Effet photoinduit</term><term>Séparation charge</term><term>Etat charge</term><term>Dispositif optoélectronique</term><term>Tension photoélectrique surface</term><term>Zinc</term><term>Composé conjugué</term><term>Matériau semitransparent</term><term>Oxyde d'indium</term><term>Carbazole</term><term>Amine aromatique polycyclique</term><term>Matériau dopé</term><term>ITO</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Zinc</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">New asymmetric porphyrins, with electroactive functionalities were synthesized. 5,15-Bis[4(-N,N-diphenylamino)phenyl]-10,20-bis[3-(N-ethylcarbazoyl)]porphyrin and its Zn(II) derivative allow the electrochemical formation of conjugated, conducting and stable polymeric films over semitransparent indium-tin oxide surface. The spectral changes observed upon oxidation of the films produced different colorations. The polymeric materials showed the generation of photoinduced charge separation states and charge migration upon porphyrin excitation, making them promising candidates for application in optoelectronics devices.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1566-1199</s0></fA01><fA03 i2="1"><s0>Org. electron. : (Print)</s0></fA03><fA05><s2>13</s2></fA05><fA06><s2>4</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Synthesis and characterization of porphyrin electrochromic and photovoltaic electropolymers</s1></fA08><fA11 i1="01" i2="1"><s1>DURANTINI (Javier)</s1></fA11><fA11 i1="02" i2="1"><s1>MORALES (Gustavo M.)</s1></fA11><fA11 i1="03" i2="1"><s1>SANTO (Marisa)</s1></fA11><fA11 i1="04" i2="1"><s1>FUNES (Matias)</s1></fA11><fA11 i1="05" i2="1"><s1>DURANTINI (Edgardo N.)</s1></fA11><fA11 i1="06" i2="1"><s1>FUNGO (Fernando)</s1></fA11><fA11 i1="07" i2="1"><s1>DITTRICH (Thomas)</s1></fA11><fA11 i1="08" i2="1"><s1>OTERO (Luis)</s1></fA11><fA11 i1="09" i2="1"><s1>GERVALDO (Miguel)</s1></fA11><fA14 i1="01"><s1>Departamento de Química, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Río Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></fA14><fA14 i1="02"><s1>Departamento de Física, Universidad Nacional de Río Cuarto, Agencia Postal Nro. 3, X5804BYA Rio Cuarto</s1><s2>Córdoba</s2><s3>ARG</s3><sZ>3 aut.</sZ></fA14><fA14 i1="03"><s1>Helmholtz Center Berlin for Materials and Energy, Institute of Heterogeneous Materials, Hahn-Meitner-Platz 1</s1><s2>14109 Berlin</s2><s3>DEU</s3><sZ>7 aut.</sZ></fA14><fA20><s1>604-614</s1></fA20><fA21><s1>2012</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>27255</s2><s5>354000509646350110</s5></fA43><fA44><s0>0000</s0><s1>© 2012 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>52 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>12-0179196</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Organic electronics : (Print)</s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>New asymmetric porphyrins, with electroactive functionalities were synthesized. 5,15-Bis[4(-N,N-diphenylamino)phenyl]-10,20-bis[3-(N-ethylcarbazoyl)]porphyrin and its Zn(II) derivative allow the electrochemical formation of conjugated, conducting and stable polymeric films over semitransparent indium-tin oxide surface. The spectral changes observed upon oxidation of the films produced different colorations. The polymeric materials showed the generation of photoinduced charge separation states and charge migration upon porphyrin excitation, making them promising candidates for application in optoelectronics devices.</s0></fC01><fC02 i1="01" i2="X"><s0>001D03F15</s0></fC02><fC02 i1="02" i2="X"><s0>001D06C02F</s0></fC02><fC02 i1="03" i2="X"><s0>230</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Porphyrine</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Porphyrin</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Porfirina</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Dispositif électrochromique</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Electrochromic device</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Dispositivo electrocrómico</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Electrochromisme</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Electrochromism</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Electrocromismo</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Propriété électrochimique</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Electrochemical properties</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Propiedad electroquímica</s0><s5>04</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Addition étain</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Tin addition</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Adición estaño</s0><s5>05</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Couche ITO</s0><s5>06</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>ITO layers</s0><s5>06</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Oxydation</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Oxidation</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Oxidación</s0><s5>07</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Effet photoinduit</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Photoinduced effect</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Efecto fotoinducido</s0><s5>08</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Séparation charge</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Charge separation</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Separación carga</s0><s5>09</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Etat charge</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="ENG"><s0>State of charge</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="SPA"><s0>Estado carga</s0><s5>10</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Dispositif optoélectronique</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="ENG"><s0>Optoelectronic device</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="SPA"><s0>Dispositivo optoelectrónico</s0><s5>11</s5></fC03><fC03 i1="12" i2="3" l="FRE"><s0>Tension photoélectrique surface</s0><s5>12</s5></fC03><fC03 i1="12" i2="3" l="ENG"><s0>Surface photovoltage</s0><s5>12</s5></fC03><fC03 i1="13" i2="X" l="FRE"><s0>Zinc</s0><s2>NC</s2><s5>22</s5></fC03><fC03 i1="13" i2="X" l="ENG"><s0>Zinc</s0><s2>NC</s2><s5>22</s5></fC03><fC03 i1="13" i2="X" l="SPA"><s0>Zinc</s0><s2>NC</s2><s5>22</s5></fC03><fC03 i1="14" i2="X" l="FRE"><s0>Composé conjugué</s0><s5>23</s5></fC03><fC03 i1="14" i2="X" l="ENG"><s0>Conjugated compound</s0><s5>23</s5></fC03><fC03 i1="14" i2="X" l="SPA"><s0>Compuesto conjugado</s0><s5>23</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Matériau semitransparent</s0><s5>24</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Semitransparent material</s0><s5>24</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Material semitransparente</s0><s5>24</s5></fC03><fC03 i1="16" i2="X" l="FRE"><s0>Oxyde d'indium</s0><s5>25</s5></fC03><fC03 i1="16" i2="X" l="ENG"><s0>Indium oxide</s0><s5>25</s5></fC03><fC03 i1="16" i2="X" l="SPA"><s0>Indio óxido</s0><s5>25</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Carbazole</s0><s5>26</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Carbazole</s0><s5>26</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Carbazol</s0><s5>26</s5></fC03><fC03 i1="18" i2="3" l="FRE"><s0>Amine aromatique polycyclique</s0><s5>27</s5></fC03><fC03 i1="18" i2="3" l="ENG"><s0>Polycyclic aromatic amines</s0><s5>27</s5></fC03><fC03 i1="19" i2="3" l="FRE"><s0>Matériau dopé</s0><s5>46</s5></fC03><fC03 i1="19" i2="3" l="ENG"><s0>Doped materials</s0><s5>46</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>ITO</s0><s4>INC</s4><s5>82</s5></fC03><fN21><s1>135</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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